Ideal Gas Law
BeginnerExplore the fundamental relationship between pressure, volume, temperature, and amount of gas.
PV = nRT
Left Side (PV):
0.00 × 50.0 = 0.00
Right Side (nRT):
2.0 × 0.0821 × 300 = 49.26
Both sides equal: ⚠️ Check
💡 How to Use:
- Free Control: Adjust any parameter independently
- Isothermal (Boyle's Law): Temperature fixed, P and V inversely related
- Isobaric (Charles's Law): Pressure constant, V and T directly related
- Isochoric (Gay-Lussac's): Volume fixed, P and T directly related
- Watch particle speed increase with temperature
- Container size changes with volume
- More moles = more particles in the container
Theory
The Ideal Gas Law
The ideal gas law describes the behavior of ideal gases by relating four fundamental properties: pressure (P), volume (V), temperature (T), and number of moles (n).
Ideal Gas Law: PV = nRT
Where:
- P = Pressure (Pa or atm)
- V = Volume (m³ or L)
- n = Number of moles
- R = Gas constant (8.314 J/(mol·K) or 0.0821 L·atm/(mol·K))
- T = Temperature (Kelvin)
Special Cases
Boyle's Law (Isothermal)
At constant temperature and amount: P₁V₁ = P₂V₂
Pressure and volume are inversely proportional.
Charles's Law (Isobaric)
At constant pressure and amount: V₁/T₁ = V₂/T₂
Volume and temperature are directly proportional.
Gay-Lussac's Law (Isochoric)
At constant volume and amount: P₁/T₁ = P₂/T₂
Pressure and temperature are directly proportional.
Avogadro's Law
At constant temperature and pressure: V₁/n₁ = V₂/n₂
Volume and moles are directly proportional.
Kinetic Molecular Theory
The ideal gas law emerges from the kinetic molecular theory, which makes the following assumptions:
- Gas particles are in constant, random motion
- Particles have negligible volume compared to container volume
- No intermolecular forces between particles
- Collisions between particles and walls are perfectly elastic
- Average kinetic energy is proportional to absolute temperature
Real vs Ideal Gases
Real gases deviate from ideal behavior under certain conditions:
- High pressure: Particle volume becomes significant
- Low temperature: Intermolecular forces become important
- Near liquefaction: Condensation effects appear
Applications
- Weather balloons: Expansion with altitude (decreasing pressure)
- Scuba diving: Air consumption and decompression calculations
- Internal combustion engines: Compression and expansion of gases
- Aerosol cans: Pressure-temperature relationships
- Hot air balloons: Volume changes with temperature
- Tire pressure: Temperature effects on pressure
- Breathing: Lung volume and pressure changes